RECEIVING your work email? Should work fine in outlook (assuming there is the right settings from your work for it), should be able to RECEIVE fine.
Sending, is another story. Many ISPs will BLOCK using someone elses OUTGOING mail server, on their ISP. This is to help prevent SPAMING, from a virus, etc on your PC using another persons ISPs info, etc.
You need to set up the OUTGOING mail server, to be a ROGERS outgoing email server, and email account info.