Not officially from Rogers, but if you go to BlackBerry App World, you download a couple apps that I use that'll do it for you.
The first one is called Call Control - It's a free application that'll allow only 5 calls to be blocked, but there is a paid version too that'll give you unlimited adds to your Blacklist. But with the five free ones, you can blocks specific numbers, or an entire area code!
The Other app, which is a must have for ANY BlackBerry user in my opinion, is SmrtGuard. I use the free version, and it works wonders. Block as many callers as I feel like, and on top of that, you also get a lot of cool security features. Check it out on their site: http://smrtguard.com/ They also have a paid version which will do an OTA backup of all your data too, but I don't use it all since I back up my phone regularly.
Good luck and I hope this helps. Oh and the Call Barring option for your berry is a feature that Rogers has not enabled for us.
You'll find me at http://www.twitter.com/javatyger when I'm not in class or playing hockey.
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